Spectrophotometric determination of vanadium in steel and iron
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چکیده
منابع مشابه
Simultaneous Spectrophotometric Determination of Vanadium(V) and Iron(III) in Micellar Medium by H-Point Standard Addition Method
H-Point Standard Addition Method (HPSAM) was applied for the simultaneous determination of V(V) and Fe(III). The method is based on the complex formation of V(V) and Fe(III) with chromazurol S (CAS) in acidic media and in the presence of cetyltrimethylammonium bromide (CTAB) as a micellizing agent. Acidic media and the presence of a micellar system improve selectivity and sensitivity. Fe (I...
متن کاملDirect and Second Order Derivative Spectrophotometric Determination of Vanadium (IV)
A new spectrophotometric method has been developed for the determination of vanadium (IV) in aqueous dimethyl formamide using 2-hydroxy-3-methoxy benzaldehyde thiosemicarbazone (HMBATC) as a chromophoric reagent. The vanadium (IV) reacts with HMBATC forming a dark yellowish green colored water soluble complex, [V(IV)–HMBATSC] in the pH range of 4.0–7.0. The yellowish green colored complex shows...
متن کاملEXTRACTIVE SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM WITH ANTHRANILIC ACID IN PRESENCE OF PYRIDINE
Vanadium (III) gives a greenish- yellow complex with anthranilic acid in presence of pyridine. The complex is extractable with chloroform and is used for photometric determination of vanadium by measuring the absorbance at 390 nm against a reagent blank. Beer's Law holds good in the range of 1-20 pg V/ml. Moderate amounts of Pb (II) , Ca (II) , Sr (II) , Ba (II) , Cd (II) , Mg (II) , Mn (II...
متن کاملKinetic-spectrophotometric determination of trace amounts of vanadium.
A simple and sensitive kinetic-spectrophotometric method is described for the determination of vanadium and the possible mechanism of catalytic reaction is proposed. The method is based on the vanadium(V)-catalyzed oxidation of 1,8-diaminonaphthalene (DNA) by potassium bromate (Tiron as activator) at pH 3.8 and 40 degrees C. The reaction was monitored spectrophotometrically by measuring the inc...
متن کاملsimultaneous spectrophotometric determination of vanadium(v) and iron(iii) in micellar medium by h-point standard addition method
h-point standard addition method (hpsam) was applied for the simultaneous determination of v(v) and fe(iii). the method is based on the complex formation of v(v) and fe(iii) with chromazurol s (cas) in acidic media and in the presence of cetyltrimethylammonium bromide (ctab) as a micellizing agent. acidic media and the presence of a micellar system improve selectivity and sensitivity. fe (iii) ...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1957
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.6.273